Hydrochemistry, mineralogy and chemical fractionation of mine and processing wastes associated with porphyry copper mines: A case study from the Sarcheshmeh mine, SE Iran     

Mehdi Khorasanipour  Majid H. Tangestani  Reza Naseh  Hamid Hajmohammadi 《Applied Geochemistry》2011,26(5):714-730

The Sarcheshmeh is one of the largest Oligo-Miocene porphyry Cu deposits in the world. Comparative hydrochemical, mineralogical and chemical fractionation associated with mining efflorescence salts and processing wastes of this mine are discussed. Hydrochemical results showed that rock waste dumps, reject wastes and old impoundments of tailings are the main sources of acid mine drainage waters (AMD) that contain potentially toxic metals such as Cd, Co, Cu, Mn, Ni and Zn as well as Al. Episodic fluxes of highly contaminated acidic waters were produced in a tailings dam over a short period of time. Secondary soluble minerals provide important controls on the quality of AMD produced, especially in old, dry tailings impoundments. Secondary sulfate minerals such as gypsum, magnesiocopiapite, hydronium jarosite, kornelite and coquimbite were found in rock waste drainages and in old weathered reject wastes. Highly soluble secondary minerals such as gypsum, eriochalcite, and bonattite are also observed in an evaporative layer on old tailings impoundments. Chemical fractionation patterns of potentially toxic elements showed that the geochemical behavior of metals is primarily controlled by the mineralogical composition of waste samples. Elements such as Co, Cr, Cu, Mn, Ni and Zn are readily released into the water soluble fraction from efflorescence salts associated with rock waste drainages, as well as from the evaporative layer of old tailings. Potentially toxic elements, such as As, Mo and Pb, are principally adsorbed or co-precipitated with amorphous and crystalline Fe oxides, but they may also be associated with oxidizing, primary sulfides and residual fractions. Following the development of the dammed tailings pond, the secondary minerals were dissolved, producing acidic waters contaminated by Al (154 mg L⁻¹), Cu (150 mg L⁻¹), Cd (0.31 m gL⁻¹), Co (2.13 mg L⁻¹), Mn (73.7 mg L⁻¹), Ni (1.74 mg L⁻¹), Zn (20.3 mg L⁻¹) and Cl (1690 mg L⁻¹). Therefore, the potential use of recycled water from the Sarcheshmenh dammed tailings pond is diminished by the presence of corrosive ions like Cl⁻ in highly acidic fluids that promote corrosion of pipes and pumps in the water recycling system.  相似文献   

Seasonal Changes in Mayfly Communities and Abundance in Relation to Water Physicochemistry in Two Rivers at Different Elevations in Northern Peninsular Malaysia     

Suhaila Abdul Hamid  Mohd Ravi Che Salmah  Hamady Dieng  Abu Hassan Ahmad  Tomomitsu Satho  Fumio Miake 《湿地科学》2011,9(3):240-250

A field study was performed at rivers in Gunung Jerai forest reserve(Kedah,Malaysia) to assess seasonal changes in mayfly community structure and abundance in relation to altitude and water physicochemistry.Rivers at lower(Batu Hampar River) and higher(Teroi River) elevations were visited through dry and wet seasons in September 2007 to August 2008.Monthly visits were made to 20 sites on each river,and water and aquatic insects were sampled using D-pond aquatic nets.Water was warmer,more acid,and more turbid in Teroi River during wet season.Ammonia was the only nutrient exhibiting significant seasonal variations(greater during wet season).Chemical oxygen demand content was higher in Teroi River where biochemical oxygen demand content was low during wet season.Species richness was higher in Batu Hampar River,but displayed seasonal variations only in Teroi River.Among the eight families encountered,Baetidae was the commonest.Baetid abundance was usually high during wet season,and those belonging to the dominant genus(Baetis) were more abundant in Teroi River.Heptageniidae was the second commonest family;its predominant genus,Thalerospyrus was more abundant in Teroi River during dry season.Caenidae,Leptophlebiidae and Oligoneuriidae were only found in Batu Hampar River where their abundances peaked during dry season,i.e.,Habrophlebiodes sp.and Isonychia sp.Ephemerellidae and Teloganodidae occurred only in Teroi River,with the first found only during dry season.Mayflies were recorded under very distinct physicochemical conditions,illustrating their potential usefulness for assessing water quality.Caenids,leptophlebids,oligoneurids ephemerellids and teloganodids seem to be particularly sensitive to temperature,acidity,turbidity,chemical oxygen demand and biochemical oxygen demand,parameters that varied with river altitude.  相似文献   

Tracing subsurface migration of contaminants from an abandoned municipal landfill   总被引：1，自引：1，他引：0  

E. A. Rahim Bahaa-eldin  I. Yusoff  S. Abdul Rahim  W. Y. Wan Zuhairi  M. R. Abdul Ghani 《Environmental Earth Sciences》2011,63(5):1043-1055

This paper aims at determining of inorganic leachate contamination for a capped unsanitary landfill in the absence of hydrogeological data. The 2D geoelectrical resistivity imaging, soil physicochemical characterization, and surface water analysis were used to determine contamination load and extent of selective heavy metal contamination underneath the landfill. The positions of the contaminated subsoil and groundwater were successfully delineated in terms of low resistivity leachate plumes of <10 Ωm. Leachate migration towards the reach of Kelang River could be clearly identified from the resistivity results and elevated concentrations of Fe in the river downslope toe of the site. Concentration of Fe, Mn, Ca, Na, K, Mg, Cu, Cr, Co, Ni, Zn, and Pb was measured for the subsoil samples collected at the downslope (BKD), upslope (BKU), and the soil-waste interface (BKI), of the landfill. The concentration levels obtained for most of the analyzed heavy metals significantly exceed the normal range in typical municipal solid waste landfill sites. The measured heavy metal contamination load in the subsoil is in the following order Fe ? Mn > Zn > Pb > Cr > Cu. Taking into consideration poor physical and chemical characteristics of the local soil, these metals first seem to be attenuated naturally at near surface then remobilize unavoidably due to the soil acidic environment (pH 4.2-6.18) which in turn, may allow an easy washing of these metals in contact with the shallow groundwater table during the periodic fluctuation of the Kelang River. These heavy metals are believed to have originated from hazardous industrial waste that might have been illegally dumped at the site.  相似文献   

Study of regional monsoonal effects on landslide hazard zonation in Cameron Highlands, Malaysia   总被引：1，自引：1，他引：0  

Abd Nasir Matori  Abdul Basith  Indra Sati Hamonangan Harahap 《Arabian Journal of Geosciences》2011,5(5):1069-1084

In general, landslides in Malaysia mostly occurred during northeast and southwest periods, two monsoonal systems that bring heavy rain. As the consequence, most landslide occurrences were induced by rainfall. This paper reports the effect of monsoonal-related geospatial data in landslide hazard modeling in Cameron Highlands, Malaysia, using Geographic Information System (GIS). Land surface temperature (LST) data was selected as the monsoonal rainfall footprints on the land surface. Four LST maps were derived from Landsat 7 thermal band acquired at peaks of dry and rainy seasons in 2001. The landslide factors chosen from topography map were slope, slope aspect, curvature, elevation, land use, proximity to road, and river/lake; while from geology map were lithology and proximity to lineament. Landslide characteristics were extracted by crossing between the landslide sites of Cameron Highlands and landslide factors. Using which, the weighting system was derived. Each landslide factors were divided into five subcategories. The highest weight values were assigned to those having the highest number of landslide occurrences. Weighted overlay was used as GIS operator to generate landslide hazard maps. GIS analysis was performed in two modes: (1) static mode, using all factors except LST data; (2) dynamic mode, using all factors including multi-temporal LST data. The effect of addition of LST maps was evaluated. The final landslide hazard maps were divided into five categories: very high risk, high risk, moderate, low risk, and very low risk. From verification process using landslide map, the landslide model can predict back about 13–16% very high risk sites and 70–93% of very high risk and high risk combined together. It was observed however that inclusion of LST maps does not necessarily increase the accuracy of the landslide model to predict landslide sites.  相似文献   

Application of spectrum–area fractal model to identify of geochemical anomalies based on soil data in Kahang porphyry-type Cu deposit,Iran     

Peyman Afzal  Hamid Harati  Younes Fadakar Alghalandis  Amir Bijan Yasrebi 《Chemie der Erde / Geochemistry》2013

The aim of this study is to identify geochemical anomalies using power spectrum–area (S–A) method based on the grade values of Cu, Mo and Au in 2709 soil samples collected from Kahang porphyry-type Cu deposit, Central Iran. S–A log–log plots indicated that there are three stages of Cu, Mo and Au enrichment. The third enrichment was considered as the main stage for the presence of Cu, Mo and Au at the concentrations above 416 ppm, 23 ppm and 71 ppb, respectively. Elemental anomalies are positively associated with monzo–granite–diorite and breccias units which are in the central and western parts of the deposit. The anomalies are located within the potassic, phyllic and argillic alteration types and also there is the positive correlation between the anomalies and nearing faults in the studied area. The results obtained via fractal model were interpreted accordingly to incorporate the information for the mineralized areas including detailed geological map, structural analysis and alterations. The results show that S–A multifractal modeling is applicable for anomalies delineation based on soil data.  相似文献   

Community-based disaster risk and vulnerability models of a coastal municipality in Bangladesh     

Md. Nazrul Islam  Md. Abdul Malak  M. Nazrul Islam 《Natural Hazards》2013,69(3):2083-2103

Bangladesh is one of the most natural hazard-prone countries in the world with the greatest negative consequences being associated with cyclones, devastating floods, riverbank erosion, drought, earthquake, and arsenic contamination, etc. One way or other, these natural hazards engulfed every corner of Bangladesh. The main aim of this research paper is to carry out a multi-hazards risk and vulnerability assessment for the coastal Matlab municipality in Bangladesh and to recommend possible mitigation measures. To this aim, hazards are prioritized by integrating SMUG and FEMA models, and a participation process is implemented so as to involve community both in the risk assessment and in the identification of adaptation strategies. The Matlab municipality is highly vulnerable to several natural hazards such as cyclones, floods, and riverbank erosion. The SMUG is a qualitative assessment, while FEMA is a quantitative assessment of hazards. The FEMA model suggests a threshold of highest 100 points. All hazards that total more than 100 points may receive higher priority in emergency preparedness and mitigation measures. The FEMA model, because it judges each hazard individually in a numerical manner, may provide more satisfying results than the SMUG system. The spatial distributions of hazard, risk, social institutions, land use, and other resources indicate that the flood disaster is the top environmental problem of Matlab municipality. Hazard-specific probable mitigation measures are recommended with the discussion of local community. Finally, this study tries to provide insights into the way field research combining scientific assessments tools such as SMUG and FEMA could feed evidence-based decision-making processes for mitigation in vulnerable communities.  相似文献   

Groundwater resources assessment using integrated geophysical techniques in the southwestern region of Peninsular Malaysia   总被引：2，自引：0，他引：2  

Mohamed S. E. Juanah  Shaharin Ibrahim  Wan Nor Azmin Sulaiman  Puziah Abdul Latif 《Arabian Journal of Geosciences》2013,6(11):4129-4144

Combined geophysical techniques such as multi-electrode resistivity, induced polarization, and borehole geophysical techniques were carried out on volcano-sedimentary rocks in the north of Gemas as part of the groundwater resource’s investigations. The result identifies four resistivity units: the tuffaceous mudstone, tuffaceous sandstone, the tuff bed, and the shale layer. Two types of aquifer systems in terms of storage were identified within the area: one within a fracture system (tuff), which is the leaky area through which vertical flow of groundwater occurs, and an intergranular property of the sandy material of the aquifer which includes sandstone and tuffaceous sandstone. The result also reveals that the aquifer occupies a surface area of about 3,250,555 m² with a mean depth of 43.71 m and a net volume of 9.798?×?10⁷?m³. From the approximate volume of the porous zone (28 %) and the total aquifer volume, a usable capacity of (274.339?±?30.177)?×?10⁷?m³ of water in the study area can be deduced. This study provides useful information that can be used to develop a much broader understanding of the nature of groundwater potential in the area and their relationship with the local geology.  相似文献   

Fractures distribution modeling using fractal and multi-fractal–neural network analysis in Tabnak hydrocarbon field, Fars, Iran     

Hamid Sarkheil  Hossain Hassani  Firuz Alinia 《Arabian Journal of Geosciences》2013,6(3):945-956

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The use of three physico-chemical methods in the study of the organic matter associated with the sedimentary phosphorites in Djebel Onk Basin, Algeria     

Mohamed Dass Amiour  Hamid Mezghache  Brahim Elouadi 《Arabian Journal of Geosciences》2013,6(2):309-319

The study of the organic matter (OM) associated with the phosphate ore of Kef Essennoun deposit (Djebel Onk mining basin, Algeria) was with a view to determine the decomposition degree of the OM within the pellets and the matrix, and the conditions of diagenesis. The sedimentary phosphates of this deposit are constituted of sub-rounded, phosphate-rich grains (pellets) dispersed in a surrounding, much poorer than pellets in P, matrix (or gangue). The survey of the OM associated with both pellets and matrix used several types of analyses: scanning electron microscopy (SEM), scanning electron microscope with energy-dispersive X-ray analysis, Fourier transform infrared spectroscopy and nuclear magnetic resonance spectroscopy. The results show the OM, dispersed approximately homogeneously, in the form of large flat particles, within the gangue and within the phosphatic pellets in the form of small particles. The O/C ratio showed that the OM is more oxidised in the matrix than within the pellets. The oxidation increased with the phosphatisation rate of the pellets and more with the carbonation rate of the matrix, but it decreased with the silicification degree in the siliceous carbonated matrix. Two major functional classes were distinguished within pellets: aliphatic and oxygenated ones, the latter being fundamentally present in humic OM. The presence and abundance of these humic compounds in pelletal phosphorites are known from the 1980s and considered as witnessing a formation of apatite in a strictly closed environment, inside the pellet.  相似文献   

A holographic reconstruction of the modified f(R) Horava-Lifshitz gravity with scale factor in power-law form     

Abdul Jawad  Surajit Chattopadhyay  Antonio Pasqua 《Astrophysics and Space Science》2013,346(1):273-278

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